Bis(μ-4-hydroxy-2-oxidobenzaldehyde 4-ethylthiosemicarbazone)-κ4 O 2,N 1,S:O 2;κ4 O 2:O 2,N 1,S-bis[chloridozinc(II)] dimethyl sulfoxide trisolvate
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چکیده
The two Zn(II) atoms in the title compound, [Zn(2)(C(10)H(12)N(3)O(2)S)(2)Cl(2)]·3C(2)H(6)OS, are each N,O,S-chelated by a mono-deprotonated Schiff base ligand. The Zn atoms are bridged through the phenolate O atom, leading to a central Zn(2)O(2) core. Each Zn atom has a Cl atom in the apical position of a distorted square-pyramidal environment. Hydr-oxy-DMSO (DMSO is dimethyl sulfoxide) O-H⋯O and amide-DMSO N-H⋯O hydrogen bonds link the components of the crystal structure. Two of the DMSO mol-ecules are partially disordered, with each modelled over two sites of equal weight.
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Bis(μ-5-hydroxy-2-{[2-(N-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl}phenolato)bis[chloridozinc(II)] N,N-dimethylformamide tetrasolvate
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